![]() Leached residues and liquid wastes are treated with either ferrous sulfate or sodium sulfide to convert chromium (VI) to chromium (III) to provide sustainable technology. Profiles of basic chromium sulfate are obtained along the height of the tower by solving mathematical models of the reactive absorption process.Ĭhromium (VI) is 99% reduced to chromium (III) in the product. The overall efficiency of conversion in the tower is increased from 70% to 80% by operating the column at optimal operating conditions obtained using response surface method.ĭispersion is achieved by random packing that provides complex countercurrent flow path resulting in greater probability of entraining gas inside the tower. Improper reduction leads to the presence of unconverted chromium (VI) that imparts toxicity, not only through product basic-chromium- sulfate but also through leather and articles produced using this chemical.ĭesign and operating conditions of the packed bed absorber were found and effects of pH, temperature and concentration of SO2 on the performance of absorption were studied. ![]() The Cr2O3 content is 23.19% and a pH of 3.01, Basic chromium sulfate available in Dark green colour.įerrochromium and chromium based compounds are produced worldwide from chromite ore.Ĭhrome chemicals are from chromium based compounds.īasic-chromium-sulfate (BCS) is a chrome chemical mostly required as main tanning agent in chrome tanning process in leather industry and also to synthesize other chromic compounds.ĭuring the preparation of basic-chromium- sulfate, sodium dichromate containing chromium (VI) is reduced to chromium (III) by sulfur-di-oxide in a packed tower at a chemical process industry (B&M Chemicals, India) where the BCS is produced at suboptimal efficiency due to inefficient (suboptimal) absorption of sulfur-di-oxide (as the gas enters the tower at a higher temperature) followed by reaction. The Basic sodium sulfate is often left in the technical product since it is inert with respect to the tanning process.īasic chromium sulfate is important to fully reduce the hexavalent chromium to trivalent since the hexavalent is more likely to cause health problems for tanners and leather consumers.īasic chromium sulfate is an inorganic compound with the chemical formula Cr(OH)(SO4).īasic chromium sulfate is a green, odorless solid at room temperature.īasic chromium sulfate is typically sold in powder form.īasic chromium sulfate has high tanning power and hence largely used in the tanning of leather.īasic chromium sulfate is easily soluble in cold water and very soluble in hot water.Ĭhromium, particularly in the hexavalent oxidation state, is toxic, hence basic chromium sulfate, which is comparatively less toxic, is preferred in the leather industry.īasic Chromium Sulphate are the mixture of various form of Chromium Sulphates including containing Chromium Hyrdoxide sulphate form chiefly.īasic chromium sulfate is prepared by the reduction of Sodium Dichromate Solution in the presence of Sulphuric Acid or Sulfur dioxide. ![]() 42% or 50% may be obtained by the addition of sodium carbonate, these are often used in combination with sodium formate. Since 33% of the anion charges are due to hydroxy ions the basicity is 33% (but in tanning jargon it is known as 33% reduced). ![]() Basic Chromium Sulphate is used in dyeing of khaki cloth and in manufacture of chrome-based dyestuffs.īasic chromium sulfate is produced from chromate salts by reduction with sulfur dioxide, although other methods exist. ![]()
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![]() One thing Overwatch players can almost certainly look forward to is the ability to unlock. As for when the event should start on that date, Blizzard usually launches new Overwatch events around 9 pm PT/12 pm. To get the latest LEGO news and LEGO Reviews straight in your inbox, subscribe via email, or you can also follow on Google News, or socials on Facebook, Twitter or subscribe to the Jay’s Brick Blog Youtube channel. Event 2022: As originally announced by Blizzard last week, the Overwatch Year of the Lunar New Year event will begin on January 25th. ![]() Remember, there’s also another Disney 100-themed GWP, 40659 Mini Steamboat Willie coming in late October so plan ahead and be strategic with your purchases to get the set that you want and maximise your GWP or Insider Points haul! The design looks to borrow influences from 6248 Volcano Island, 6279 Skull Island and 6234 Renegade’s Raft, as well as incorporating some spooky Halloween vibes thanks to the Shark Head cave, and bats.Ĭombined with the upcoming Double Insider Points event from 10-15 October 2023, you should be able to score a decent deal if you have a large enough purchase coming up. I believe it should be close to around the US$100 mark on all purchases on .įor fans of Classic Pirates, it’s a pretty neat GWP, with the minifigure sporting the same torso as the Pirate Captain from the Creator 31109 Pirate Ship. 2019: January 24 to February 18 (Year of the Pig) 2020: January 16 to February 5 (Year of the Rat) 2021: February 4 to February 25 (Year of the Ox) 2022. We don’t have official purchase threshold details yet, but I don’t think this GWP will have an unreasonably high threshold. Overwatch - Overwatch Lunar New Year 2019 Seasonal Event Trailer. 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Its Winter Wonderland event - which brought a new Winter brawl, new cosmetics, more achievements, and rewards - had only just finished when the Kanezaka Challenge went live, with a new Kanezaka deathmatch map featuring a pottery workshop and cat cafe, as well as more rewards and challenges. Roar into 2022 with Overwatch’s Lunar New Year event, which is now live on all platforms and runs from Jan. The next Overwatch event has a January 25 release date and a 6pm GMT start time for players living in the UK. The world could always use more fireworks.Celebrate with new festive rewards, cosmetics, and the new Bounty Hunter brawl. Last year's, the Year of the Rat, brought weekly challenges, themed rewards like emotes and sprays, a new version of Capture the Flag, and new skins for Winston, Doomfist, and Wrecking Ball. Overwatch fans are counting down to the start of the Lunar New Year event. Blizzard isn't sharing too many details just yet, aside from a highlight intro for D.Va, but we can get an idea of what's to come from the game's previous limited-time Lunar New Year events. ![]() Overwatch: Origins Edition Blizzard Entertainment Local Multiplayer Online Multiplayer First Person Shooter Heidi Nicholas You don't have long to wait until Overwatch's next Lunar New Year event: Year of the Ox, a limited-time event, begins this week on February 4th, and runs for the next three weeks until February 25th. ![]() ![]() ![]() ![]() We can be reached through our online contact form and will be happy to answer any questions you may have regarding our services. To learn more about scaffold pricing or to inquire about one of our scaffold system rentals, get in touch with the team at United Scaffold Supply. 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![]() ![]() Other than that, it is one of the best of this series and very close to perfect. Following along to the words also helps children. Hakuna Matata is fine, but Yummy Yummy, W-I-L-D and Jungle Rhythm are forgettable and very unnecessary, at least in my opinion. This program provides sing along songs of the Circle of Life from the wonderful Disney story The Lion King. What makes Circle of Life not quite perfect? The added songs for me. The timeless magic that is Disney music begins here with the very best from The Early Years (1933-1949). Anybody who loves Jiminy Cricket will find him every bit as likable and as thoughtful, and we are treated to Cliff Edward's immortal rendition of When You Wish Upon a Star from Pinocchio, one of the most inspiring and heart-melting Disney songs of their cannon, not to mention nostalgic. Lets sing a song in this 2003 DVD of Disneys Sing Along Songs: The Lion King: Circle of Life.Previews Order:The Lion King: Special EditionRolie Polie Olie. The third series, which began with 1994s Circle of Life, saw another new package design and the re-release of all previous volumes (excluding Fun with Music. Other highlights are the poignant Part of Your World, the fun and underrated Prince Ali, the jazzy Everybody Wants to be a Cat and Belle, which sets the tone of Beauty and the Beast beautifully. With more than 40 musical instruments used, discover how the Pridelands are brought to life with sound through The Lion King music and songs. Released in December of 1994, the 30 minute ta. I Can't Wait to be King looks just as vibrant and great fun, but Circle of Life gives me that extra something. This video consists of the opening previews for the Circle of Life volume of Disneys Sing-Along Songs series. Circle of Life starts wonderfully, with one of the best and spirit-rousing beginnings of any Disney movie(my favourite is the one for The Hunchback of Notre Dame) in Circle of Life. This Christmas gave me an opportunity to revisit these sing-along videos, and Circle of Life turned out to be one of my favourites. And The Lion King is my second favourite Disney film after Beauty and the Beast. I love Disney, and the Disney Sing-along series. Web1994 VHS of Disney Sing Along Songs: Circle of Life. Waters), Maxine Waters Willard (as Maxine Waters), Oren Waters, John J West, Yvonne Williams, Terry Young, Zolile Zulu Circle of life sing along songs Lion King Circle Of Life Sing-Along Part 1: Circle Of Life Lot of 11 Disney Sing Along Songs VHS Tapes - Vintage - Circle of. Disney Sing Along Songs : Free Download, Borrow, and Streaming. Stevens), Khuluiwe Sithole (as Khuluiwe S'thole), Thandazile, Carmen Twillie, Sam Vamplew, Julia Waters, Luther Waters (as Luther N. Mariri, Myrna Matthews, Batho Mhlongo, Vusi Mhlongo, Nonhlanhla Mkhize, Thembi Mtshali, Bheki Ndlovu, Nandi Ndlovu, Bongani Ngcobo, Nini Nkosi, Bobbi Page, Phindile, Rick Riso, Philile Seme, Alfie Silas, Happy Skhakhane, Kipizane Skweyiya, Sindisiwe Sokhela, Susie Stevens-Logan (as Susan D. Disney Sing-Along Songsa is a series of videos on VHS, betamaxs, laserdiscs and DVDs with musical moments from various Disney films, TV shows and attractions. Background Singer: Rodney Saulsberry Chorus: Maxi Anderson, Terry Bradford, Johnny Britt, Baby Cele, Lucky Cele, Rick Charles, Gugwana Dlamini, Kevin Dorsey, Wendy Fraser, Linda Gcwensa, Clydene Jackson (as Clydene Jackson), Matoab'sane Jali, Luyanda Jezile, Bob Joyce, Faith Kekana, Sphiwe Khanyile, Faca Khulu, Stella Khumalo, Skhumbuzo Kubheka, Thembi Kubheka, Ron Kunene, James Langa, Edie Lehmann Boddicker, Rick Logan, Tsidi Manye, Khanyo Maphumulo, Abner A. This is the VHS Opening and Closing to Disneys Sing-Along Songs Circle of Life VHS Tape and Heres the Order1. Join Jiminy Cricket as he hosts this Sing-Along-Songs video with music from The Lion King, The Little Mermaid. ![]() Here’s a list of songs from both versions of Disney’s Sing Along Songs series 3 volume 1 – “Circle of Life”, which was hosted on its original version by Jiminy Cricket.Circle of Life Music by Elton John Lyrics by Tim Rice Arranged and Produced by Hans Zimmer Performed by Carmen Twillie African Vocals Performed by Lebo M. Courtesy of Eli Hechtmans DSAS Japanese laserdisc: Circle Of Life. ![]() Thus, that animated classic’s main theme is the central song for the volume, which was later re-released in 2003 with additional songs from some animated series and home video animated films. Disneys Sing Along Songs Circle Of Life Hosting Segments. The concluding volumes of the second series of Disney’s Sing Along Songs home video franchise following “A Friend Like Me” in 1993 were all mostly original and traditional songs outside of the Disney musical library barring a few selections one of the volumes in fact was yet another Christmas album.Ĭome 1994 however, a third series of the whimsical Disney karaoke was begun, with its inaugural volume released in time to celebrate the then-recent premiere of The Lion King. ![]() ![]() ![]() This theory of course entails that the qualities of the bread and wine are real entities distinct from their substances.” But the accidents of the bread and wine remain (without inhering in the newly present body and blood of Christ, or in any other substance). ![]() That theory holds that at the moment of consecration the bread and wine of the sacrament cease to exist and are replaced by the body and blood of Christ. Ockham does not explicitly address this question, but it is tempting to suppose the answer lies in the doctrine of the Eucharist interpreted according to the theory of transubstantiation. None of the richness of the world would be lost, only the illusion that we need distinct entities for all the different claims we want to make about things. ![]() Substances would be qualified, quantified, related in different ways, would variously act and be acted upon, and so on, but there would be only substances. In that case, we would end up with a single ontological category: Why is it not just as legitimate to say things are really ‘qualified’ but there are no qualities – things are really white or red, hot or cold, although there is no whiteness or redness, no heat or cold as a distinct accidental entity in the category of quality? If other categories can be eliminated without denying any of the ways things really are, why not quality too? “He allows individual qualities, for example there are as many whitenesses as there are white things (although there is no universal whiteness). Ockham ‘eliminates’ all the Aristotelian categories in this way – except for substance and quality.” Things really act, but there are no actions things are really related without relations (except for the few exceptional cases required by theology). “Ockham is prepared to say things really act or are acted on, are really related to one another, and so on, but he does not think the truth of these statements requires us to postulate real entities in the categories of action, passion, or relation. The following OntoUML diagram presents the main classes of Ockham’s ontology: Likewise, if both are black, or hot, they are similar without anything else added.“ Thus, from the very fact that Socrates is white and Plato is white, Socrates is similar to Plato and conversely.
![]() ![]() Next, choose the third gradient from the left – the Black to White gradient. So, let’s get the Gradient tool from the Toolbar, and once you have it, go up the Options bar, and up near the top left, click on the down-facing arrow to the right of the currently selected gradient to bring up the Gradient picker. One of my favorite ways to blend images using a layer mask is to use the Gradient tool. This will make more sense in a minute, but if you keep that line in mind – “black conceal and white reveal,” it will help you when you’re not sure what to do next. So, if you painted in black on that white layer mask, it hides whatever you painted over. If it’s solid white, you can fully see everything on that layer. If the layer mask is solid black, whatever on that is hidden. If you took a paintbrush and painted with White as your foreground color, wherever you painted, it would reveal what’s on that layer. ![]() OK, before we head to the next step, it’s time to lay one of the old sayings about layer masks, which has been around for 200+ years, and that is, “Black conceals and white reveals.” If your layer mask is black, whatever is on that layer is hidden from view. This adds a white layer mask to this layer (you can see it in the Layers panel – it’s the white rectangle that appears to the right of the Layer). Go to the bottom of the Layers panel and click the “Add Layer Mask” button, as shown here (it’s the 3rd icon from the left and looks like a rectangle with a circle cut out of the center). Now switch to your Piano document (or whichever image you’re using as your background image) go under the Edit menu and choose ‘Paste’ to paste your red rose image on top of the piano image. Press Command-A (PC: Ctrl-A) to select the entire image and then go under the Edit menu and choose ‘Copy’ to copy the red rose image into memory. Now click on the tab for the first image you want to blend with the piano image (in this case, we’ll choose the red rose). Open the piano image (or whatever image you want to use as the background for your collage). If you choose one of those arrangements for your images and want to get back to our regular view, go under that same menu and select ‘Consolidate All To Tabs.” You choose these document “arrangements” by going under Photoshop’s Window menu, under Arrange, and making your choice there (I chose 3-up Vertical). By the way – there is a Photoshop feature that puts your images side-by-side on screen like this (it just resizes your documents so they fit on screen either horizontally or vertically, as I did here). I’m making them available for you to download if you want to follow along using the same images, but I encourage you to use three of your own images. Let’s open the three images we’re going to put together (seen here). ![]() We’ll start by blending three images together, creating a collage (or a montage, or whatever you call it). However, they still allow you to do things you can’t do in Lightroom, so they are definitely worth knowing, and they open a whole new world of Layers possibilities, so this is still really big important stuff. Today we’re talking about using Layer Masks (finally!), which are fantastic, but now that there are a bunch of new masking features inside of Lightroom, you probably won’t have to use Layer Masks as often as you would have before. This week wraps up the Layers portion of our Photoshop journey, so next week, we’ll open a new can of worms…er, I mean some other important Photoshop features. Welcome back once again and by now, you’re probably getting a little tired of the whole learning Layers thing, but I have good news. ![]() ![]() ![]() The sound of a cat purring is so magical and proven to be comforting that there is even an app to simulate the sound. Want to share this exotic and refreshing treat with your favorite bundle of fur? Munchiecat’s Matcha and Berry Ice Cream Cones include crinkle paper and a rattle.← Blog 10 Things You Didn’t Know About Cat Purrs It’s made with a bittersweet, earthy green tea powder and sweet chilled cream. Matcha or green tea ice cream is a popular Japanese dessert. Purring can also build muscles, increase flexibility, and reduce swelling. Purring causes low-frequency vibrations between 25 and 150 Hertz that can heal open wounds and broken bones. Purring is also like built-in physical therapy for cats. It reduces their pain and helps them breathe easier. In these cases, purring is soothing to cats, like a baby sucking a pacifier. ![]() Some cats purr while they’re giving birth or dying. Your cat is trying to heal herself and relieve pain. Scientists also found that people who don’t have any cats can distinguish between normal purrs and ‘please give me some food’ purrs.Ħ. A 2009 study in Current Biology found cat owners are more likely to respond to these higher-pitched purrs. They’re like the wailing of a newborn human baby. These ‘food soliciting’ purrs sound more urgent and unpleasant. Swedish researchers found that cats purr more when they’re reunited with their humans after a long period of separation.Ĭats may also purr when they feel hungry and want food. Some cats purr when they are lonely and want your attention. It reminds them of being snuggled close to their mom and receiving on-demand meals. Many adult cats will knead on soft surfaces like blankets, pillows, or laps while purring up a storm. This is called kneading or “making biscuits” because it looks like a person making dough. When they find their mother’s teats, newborn kittens push their front paws up and down while purring until milk comes out. Mother cats also purr to help their kittens find their first meal. This makes it harder for predators to find newborn kittens. Purring is also quieter than other cat sounds like chattering and meowing. When newborn kittens purr, they send their mother an “all is well” signal.īecause newborn kittens can’t regulate their own body temperature until they’re 4 weeks old, mother cats purr to keep them warm. While they can’t hear or see until they’re 10 days old, newborn kittens can purr at just 2 days old. As a way for kittens and mother cats to communicate Purring releases brain chemicals called endorphins that kill pain and create a general feeling of well-being. If she is scared or stressed out, she may purr at a higher pitch while baring her teeth or panting. ![]() Whether it’s a change in your inner circle or a visit to the vet, your cat may purr to self-soothe and calm down. Your cat has anxiety.Ī sudden shift in your cat’s environment or routine can trigger feline anxiety. " Or your cat may be asking other household felines to share resources like the litter box. But purring could be your cat's way of telling other family pets, " I’m not a threat. What your cat is trying to say exactly isn't clear to feline researchers yet. (Think of the sniffer-to-sniffer greeting as a de facto feline handshake.) But your kitty may also make a “prrt” sound. Ĭats also touch noses to greet each other. ![]() Social grooming (or allogrooming) helps cats mix their individual smells together to form a family scent. Your cat won’t groom unfamiliar cats, according to the Journal of Feline Medicine and Surgery. Purring is a sign that your cat has formed a close friendship with another household cat.īonded cats usually purr when they groom each other. ![]() ![]() But yeah I don't think they'll address the db performance.I'm just saying don't exclude it just on that. I agree it's slower for larger news groups, but it's ok once it gets the db loaded. The original authors do work on it from time to time, just not regularly. However, the addition of yEnc support and detection of complete binaries were both added after developent ceased and that message was posted. Likewise, it was "unacceptably slow" on the system I used at the time it may be tolerable on today's hardware.And as I said in the sentance right after that, no official development does occur. At the time, there were no plans for further development. ![]() Quote:Originally posted by Zarquon:Coleman: quote:In defense of Gravity, it's not quite abandoned but it's not being worked on heavily anymore since it doesn't exist as a commercial enterprise anymore. This is good for really active groups where that would take a while. View image here: -Another thing I like is that I can set the prefs so that when I click on a group in the left pane, it just loads the cached headers without downloading new ones automatically. Oh yeah, it also has built-in image display for those, ahem, image-heavy newsgroups. Plus there's a little button you can click to take it "offline" to pause a big download, and it resumes at the same spot later on. For binaries, it's really good, handling multipart, yEnc, and other stuff with ease. View image here: - Apparently there's now a Win32 version as well I haven't tried it but it should be good, if it's anything like the Linux version.It's pretty good for text newsgroups, as I can just hit space to page through a message, and then hitting space again when it's at the end moves on to the next message in the thread. Originally that was PAN, for Pimp Ass Newsreader, but apparently they're trying to make it more professional now. Newsrover does them faster but I still haven't found anything I liked the interface on as much as Gravity.Also, as I don't know much about the other readers(I've invested in Newsrover so I'm more tied to it) here are features I like about Newsrover:index searching - can interface with the indexes of many major news providers and search the indexes withouth downloading all the headerssome basic features for managing decoded files(easy filing etc)built in PAR/PAR2 support for recovery when missing pieces are foundCRC based duplicate checking database(good pr0n management!) - View image here: -Automated downloads and server limit tracking.I'm sure others have at least some of these features too.Oh, also Newsrover has a special fully functional version available free of cost if you are a subscriber setup(hard coded I think) for their servers. ![]() yEnc) they got added by the original authors.But I agree it can take some time to process newsgroups with large numbers of articles. But when major features were needed to make it continue being viable(i.e. In defense of Gravity, it's not quite abandoned but it's not being worked on heavily anymore since it doesn't exist as a commercial enterprise anymore. ![]() |
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